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Potential for Recovery of Cerium Contained in Automotive Catalytic Converters

机译:汽车催化转化器中铈的回收潜力

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摘要

Catalytic converters (CATCONs) are required by Federal law to be installed in nearly all gasoline- and diesel-fueled onroad vehicles used in the United States. About 85 percent of the light-duty vehicles and trucks manufactured worldwide are equipped with CATCONs (Ashok Kumar, Director, A–1 Specialized Services \u26 Supplies, Inc., written commun. July 10, 2012). These vehicles include buses, cars, light- and heavy-duty trucks, and motorcycles. Many offroad vehicles, such as trail bikes and all-terrain recreational vehicles, are also equipped with CATCONs, but offroad vehicles are not addressed in this paper (Manufacturers of Emission Controls Association, 2008).Portions of the CATCONs (called monoliths) are recycled for their platinum-group metal (PGM) content and for the value of the stainless steel they contain. The cerium contained in the monoliths, however, is disposed of along with the slag produced from the recycling process. Although there is some smelter capacity in the United States to treat the monoliths in order to recover the PGMs, a great percentage of monoliths is exported to Europe and South Africa for recycling, and a lesser amount is exported to Japan. There is presently no commercial-scale capacity in place domestically to recover cerium from the monoliths.Recycling of cerium or cerium compounds from the monoliths could help ensure against possible global supply shortages by increasing the amount that is available in the supply chain as well as the number and geographic distribution of the suppliers. It could also reduce the amount of material that goes into landfills. Also, the additional supply could lower the price of the commodity. This report analyzes how much cerium oxide is contained in CATCONs and how much could be recovered from used CATCONs.
机译:联邦法律要求在美国使用的几乎所有以汽油和柴油为燃料的公路车辆上都必须安装催化转化器(CATCON)。全球制造的轻型车辆和卡车中约有85%配备了CATCON(A-1特种服务公司总监,Ashok Kumar,书面公报,2012年7月10日)。这些车辆包括公共汽车,汽车,轻型和重型卡车以及摩托车。许多越野车(例如越野车和全地形休闲车)也配备了CATCON,但本文未涉及越野车(排放控制协会制造商,2008).CATCON的某些部分(称为整体式)被回收。其铂族金属(PGM)含量以及所含不锈钢的价值。但是,将整料中所含的铈与回收过程中产生的炉渣一起处理。尽管美国有冶炼厂处理整料以回收PGM的能力,但很大一部分整料出口到欧洲和南非进行回收,而少部分则出口到日本。目前国内尚无从大规模生产中回收铈的商业规模的能力。从大规模生产中回收铈或铈化合物可通过增加供应链和供应链中可用的数量来帮助防止可能的全球供应短缺。供应商的数量和地理分布。它还可以减少进入垃圾填埋场的材料量。另外,额外的供应可能会降低商品的价格。该报告分析了CATCON中包含的氧化铈含量,以及可以从使用过的CATCON中回收多少氧化铈。

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    Bleiwas, Donald I.;

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